A molecular Debye-Hückel approach to the reorganization energy of electron transfer reactions in an electric cell.

Reorganization energy of electron transfer processes in ionic fluids: a molecular Debye-Hückel approach.

The reorganization energy of electron transfer processes in ionic fluids is studied under the linear response approximation using a molecule Debye-Hückel theory. Reorganization energies of some model reactants of electron transfer reactions in molten salts are obtained from molecular simulations and a molecule Debye-Hückel approach. Good agreements between simulation results and the results fro...

Reorganization Energy of Electron Transfer Processes in Ionic Fluids: A Molecular Debye-HÃ1⁄4ckel Approach

Solvent reorganization in electron and ion transfer reactions near a smooth electrified surface: a molecular dynamics study.

Molecular dynamics simulations of electron and ion transfer reactions near a smooth surface are presented, analyzing the effect of the geometrical constraint of the surface and the interfacial electric field on the relevant solvation properties of both a monovalent negative ion and a neutral atom. The simulations show that, from the solvation point of view, ion adsorption is an uphill process d...

Extensions to Study Electrochemical Interfaces - A Contribution to the Theory of Ions

In the present study an alternative model allows the extension of the Debye-Hückel Theory (DHT) considering time dependence explicitly. From the Electro-Quasistatic approach (EQS) done in earlier studies time dependent potentials are suitable to describe several phenomena especially conducting media as well as the behaviour of charged particles in arbitrary solutions acting as electrolytes. Thi...

Nuclear electron capture rate in stellar interiors and the case of 7 Be

Nuclear electron capture rate from continuum in an astrophysical plasma environment (like solar core) is calculated using a modified Debye–Hückel screening potential and the related non-Gaussian q-distribution of electron momenta. For q = 1 the well-known Debye–Hückel results are recovered. The value of q can be derived from the fluctuation of number of particles and temperature inside the Deby...